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Activation of Raman modes in monolayer transition metal dichalcogenides through strong interaction with gold

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00557856" target="_blank" >RIV/61388955:_____/22:00557856 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/22:10444777

  • Result on the web

    <a href="http://hdl.handle.net/11104/0331698" target="_blank" >http://hdl.handle.net/11104/0331698</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1103/PhysRevB.105.195413" target="_blank" >10.1103/PhysRevB.105.195413</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Activation of Raman modes in monolayer transition metal dichalcogenides through strong interaction with gold

  • Original language description

    Raman spectroscopy has become one of the most utilized methods for the characterization of transition metal dichalcogenides (TMDCs). However, the interpretation of the Raman spectra of TMDC-based heterostructures has been the subject of recent debate. Using a comprehensive combination of micro-Raman and tip-enhanced Raman spectroscopy, accompanied by ab initio simulations of both Raman frequencies and intensities, we show that the activation of the otherwise geometry-forbidden E mode and symmetry-forbidden A1 mode is the fingerprint of the strong interaction between the monolayer MX2 (M is Mo/W, X is S/Se) and the gold substrate, in contrast to the weakly interacting or freestanding MX2.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Review B

  • ISSN

    2469-9950

  • e-ISSN

    2469-9969

  • Volume of the periodical

    105

  • Issue of the periodical within the volume

    19

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

    195413

  • UT code for WoS article

    000805565000002

  • EID of the result in the Scopus database

    2-s2.0-85130601582