A polarizable reference electrode
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00560601" target="_blank" >RIV/61388955:_____/22:00560601 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0333466" target="_blank" >https://hdl.handle.net/11104/0333466</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.elecom.2022.107354" target="_blank" >10.1016/j.elecom.2022.107354</a>
Alternative languages
Result language
angličtina
Original language name
A polarizable reference electrode
Original language description
A problem often encountered in polarization studies at water (w)/organic solvent (o) interfaces is the poor stability of the potential of the reference electrode connected to the organic solvent phase (o). The potential of this reference electrode is usually based on the partition of a highly hydrophobic cation between the reference water (wʹ) and the organic solvent phase (o). The deterioration in stability is associated with the spontaneous extraction of a salt containing a common cation from the phase (wʹ) to the phase (o), which leads to a significant shift in the reference potential. In the present study, the novel concept of a polarizable reference electrode is introduced, which makes it possible to resolve this problem in a sophisticated way. The solution makes use of a polarizable metal electrode, the potential of which is adjusted by a battery-operated three-electrode potentiostat, and which then serves as a reference organic solvent electrode in a four-electrode system for the polarization of the water/organic solvent interface.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
<a href="/en/project/GA22-32631S" target="_blank" >GA22-32631S: Anomalous salt extraction from water to polar organic solvents: A novel mechanism of the spontaneous emulsification and practical application</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrochemistry Communications
ISSN
1388-2481
e-ISSN
1873-1902
Volume of the periodical
141
Issue of the periodical within the volume
AUG 2022
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
3
Pages from-to
107354
UT code for WoS article
000850013200002
EID of the result in the Scopus database
2-s2.0-85136136121