Gas Phase C6H6− Anion: Electronic Stabilization by Opening of the Benzene Ring

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00564997" target="_blank" >RIV/61388955:_____/22:00564997 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/22:00564997
Result on the web
<a href="https://hdl.handle.net/11104/0337491" target="_blank" >https://hdl.handle.net/11104/0337491</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1063/5.0130998" target="_blank" >10.1063/5.0130998</a>

Result language
angličtina
Original language name
Gas Phase C6H6− Anion: Electronic Stabilization by Opening of the Benzene Ring
Original language description
It is well established that an isolated benzene radical anion is not electronically stable. In the present study, we experimentally show that electron attachment to benzene clusters leads to weak albeit unequivocal occurrence of a C6H−6 moiety. We propose here—based on electronic structure calculation—that this moiety actually corresponds to linear structures formed by the opening of the benzene ring via electron attachment. The cluster environment is essential in this process since it quenches the internal energy released upon ring opening, which in the gas phase leads to further dissociation of this anion.
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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