Vibrational excitation in the e + CO2 system: Analysis of the two-dimensional energy-loss spectrum
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00566830" target="_blank" >RIV/61388955:_____/22:00566830 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11320/22:10456308
Result on the web
<a href="https://doi.org/10.1103/PhysRevA.106.062807" target="_blank" >https://doi.org/10.1103/PhysRevA.106.062807</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1103/PhysRevA.106.062807" target="_blank" >10.1103/PhysRevA.106.062807</a>
Alternative languages
Result language
angličtina
Original language name
Vibrational excitation in the e + CO2 system: Analysis of the two-dimensional energy-loss spectrum
Original language description
We present a detailed analysis of the two-dimensional electron energy-loss spectrum of CO2, which extends our recent Letter [Phys. Rev. Lett. 129, 013401 (2022)0031-900710.1103/PhysRevLett.129.013401]. We show that our vibronic coupling model [Phys. Rev. A 105, 062821 (2022)2469-992610.1103/PhysRevA.105.062821] captures primary features of the multidimensional dynamics of the temporary molecular anion, and the calculations qualitatively reproduce the spectrum. The shape of the spectrum is given by two overlapping contributions that originate in excitation of vibrational states within ςg+ and Πu Fermi polyads. Propensity rules in terms of scattered and vibrational wave functions are also discussed to clarify the selectivity of states from the vibrational pseudocontinuum that is responsible for the observed fine structure.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physical Review A
ISSN
2469-9926
e-ISSN
2469-9934
Volume of the periodical
106
Issue of the periodical within the volume
6
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
062807
UT code for WoS article
000901724300001
EID of the result in the Scopus database
2-s2.0-85143647594