Electrochromic 2,5-Dihydroxyterephthalic Acid Linker in Metal−Organic Frameworks
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00568164" target="_blank" >RIV/61388955:_____/22:00568164 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0339502" target="_blank" >https://hdl.handle.net/11104/0339502</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adpr.202100219" target="_blank" >10.1002/adpr.202100219</a>
Alternative languages
Result language
angličtina
Original language name
Electrochromic 2,5-Dihydroxyterephthalic Acid Linker in Metal−Organic Frameworks
Original language description
Metal–organic frameworks (MOFs) are diverse in color owing to a large variety of molecular structures. Herein, electrochromism of M-MOF-74 (M = Mg, Mn, Co or Zn) is reported, which is a honeycomb nano-framework in which hexagonally packed 1D arrays of metal cations are coordinated with 2,5-dihydroxyterephthalic (dhtp) acid linker. Raman spectroscopy upon electrochemical doping combined with density functional theory calculations reveals redox reactions of the linker while the metal cations stay divalent as probed by X-ray photoemission spectroscopy (XPS). Excellent adhesion of the MOFs to glass allows the synthesis of quality thin films to be implemented into electrochromic devices that exhibit promising color contrast and durability.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Advanced Photonics Research
ISSN
2699-9293
e-ISSN
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Volume of the periodical
3
Issue of the periodical within the volume
4
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
2100219
UT code for WoS article
000969259600004
EID of the result in the Scopus database
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