A Novel Molecular Assembly of a Cobalt-Sulfate Coordination Polymer and Melamine: A Manifestation of Magnetic Anisotropy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F23%3A00567964" target="_blank" >RIV/61388955:_____/23:00567964 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0339274" target="_blank" >https://hdl.handle.net/11104/0339274</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsomega.2c07556" target="_blank" >10.1021/acsomega.2c07556</a>
Alternative languages
Result language
angličtina
Original language name
A Novel Molecular Assembly of a Cobalt-Sulfate Coordination Polymer and Melamine: A Manifestation of Magnetic Anisotropy
Original language description
A novel molecular assembly of a cobalt-sulfate coordination polymer and melamine is synthesized under acidic conditions. Bar-shaped pink monocrystals as long as 1 mm are found to align along magnetic field lines in the proximity of a strong magnet. Magnetometry shows no hysteresis at temperatures down to 2 K but instead magnetic anisotropy and antiferromagnetic coupling. X-ray diffraction on a single crystal reveals that the cobalt-sulfate chains are along the shortest lattice vector or the crystal's long axis. The crystal alignment along the magnetic flux can be attributed to single-ion anisotropy that results in longitudinal antiferromagnetic coupling along the chain. Both structurally and magnetically isotropic crystals of metal-organic hybrid materials can be highly useful as elemental components in magneto-optics.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Omega
ISSN
2470-1343
e-ISSN
2470-1343
Volume of the periodical
8
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
3493-3500
UT code for WoS article
000913362200001
EID of the result in the Scopus database
2-s2.0-85146132870