Cyclotrimerization Approach to Symmetric [9]Helical Indenofluorenes: Diverting Cyclization Pathways
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F23%3A00574039" target="_blank" >RIV/61388955:_____/23:00574039 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/23:10474365
Result on the web
<a href="https://hdl.handle.net/11104/0344406" target="_blank" >https://hdl.handle.net/11104/0344406</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.202301491" target="_blank" >10.1002/chem.202301491</a>
Alternative languages
Result language
angličtina
Original language name
Cyclotrimerization Approach to Symmetric [9]Helical Indenofluorenes: Diverting Cyclization Pathways
Original language description
Catalytic cyclotrimerization routes to symmetrical [9]helical indenofluorene were explored by using different transition–metal complexes and thermal conditions. Depending on the reaction conditions, the cyclotrimerizations were accompanied by dehydro-Diels–Alder reaction giving rise to another type of aromatic compounds. Structures of both symmetrical [9]helical cyclotrimerization product as well as the dehydro-Diels–Alder product were confirmed by single-crystal X-ray diffraction analyses. Limits of enantioselective cyclotrimerization were assessed as well. DFT calculations shed light on the reaction course and the origin of diminished enantioselectivity.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GF21-39639L" target="_blank" >GF21-39639L: Catalytic Cyclotrimerization and C-C/C-H Functionalization Reactions in the Synthesis of Functional Molecules</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
1521-3765
Volume of the periodical
29
Issue of the periodical within the volume
58
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
e202301491
UT code for WoS article
001033139400001
EID of the result in the Scopus database
2-s2.0-85165274945