Selectivity of Mn rich Ru Mn O phases in parallel oxygen and chlorine evolution
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F24%3A00585923" target="_blank" >RIV/61388955:_____/24:00585923 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0013468624005887" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0013468624005887</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2024.144346" target="_blank" >10.1016/j.electacta.2024.144346</a>
Alternative languages
Result language
angličtina
Original language name
Selectivity of Mn rich Ru Mn O phases in parallel oxygen and chlorine evolution
Original language description
Single phase Mn rich RuxMn1-x O2 conforming to a highly disordered γ MnO2 with pyrolusite-like blocks dominating in the structure were prepared in the low Ru content range (0.15 ≥ x ≥ 0.30). All synthesized materials were electrochemically active in oxygen and chlorine evolution in acidic media with variable chloride content. The total anodic activity increased with increasing Ru content in the structure as well as with increasing concentration of chlorides in the solution. The selectivity towards oxygen evolution reaction was predominant for all chloride concentrations (from 0.02 to 0.3 M), and its value was not dependent on the total Ru content in the material structure. The reaction mechanism with respect to chlorine evolution reaction was discussed on the basis of the determined order of reactions, which apparently increases with increasing Ru content.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrochimica acta
ISSN
0013-4686
e-ISSN
1873-3859
Volume of the periodical
492
Issue of the periodical within the volume
JUL 2024
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
144346
UT code for WoS article
001240391800001
EID of the result in the Scopus database
2-s2.0-85192326465