Electron-induced ligand loss from iron tetracarbonyl methyl acrylate

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F24%3A00587757" target="_blank" >RIV/61388955:_____/24:00587757 - isvavai.cz</a>

Alternative codes found

RIV/60461373:22340/24:43929458

Result on the web

<a href="https://hdl.handle.net/11104/0354853" target="_blank" >https://hdl.handle.net/11104/0354853</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3762/bjnano.15.66" target="_blank" >10.3762/bjnano.15.66</a>

Result language

angličtina

Original language name

Electron-induced ligand loss from iron tetracarbonyl methyl acrylate

Original language description

We probe the separation of ligands from iron tetracarbonyl methyl acrylate (Fe(CO)4(C4H6O2) or Fe(CO)4MA) induced by the interaction with free electrons. The motivation comes from the possible use of this molecule as a nanofabrication precursor and from the corresponding need to understand its elementary reactions fundamental to the electron-induced deposition. We utilize two complementary electron collision setups and support the interpretation of data by quantum chemical calculations. This way, both the dissociative ionization and dissociative electron attachment fragmentation channels are characterized. Considerable differences in the degree of precursor fragmentation in these two channels are observed. Interesting differences also appear when this precursor is compared to structurally similar iron pentacarbonyl. The present findings shed light on the recent electron-induced chemistry of Fe(CO)4MA on a surface under ultrahigh vacuum.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10403 - Physical chemistry

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2024

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Beilstein Journal of Nanotechnology

ISSN

2190-4286

e-ISSN

2190-4286

Volume of the periodical

15

Issue of the periodical within the volume

JUL 2024

Country of publishing house

DE - GERMANY

Number of pages

11

Pages from-to

797-807

UT code for WoS article

001263222200001

EID of the result in the Scopus database

2-s2.0-85200348639