Catalytic dehalogenation with activated borane, a porous borane cluster polymer
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F24%3A00588410" target="_blank" >RIV/61388955:_____/24:00588410 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/24:00588410 RIV/60461373:22310/24:43929450
Result on the web
<a href="https://hdl.handle.net/11104/0355397" target="_blank" >https://hdl.handle.net/11104/0355397</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d4cy00732h" target="_blank" >10.1039/d4cy00732h</a>
Alternative languages
Result language
angličtina
Original language name
Catalytic dehalogenation with activated borane, a porous borane cluster polymer
Original language description
Activated borane (ActB), a metal- and halogen-free porous borane cluster polymer with a significant Lewis acidity, has been successfully used as a heterogeneous catalyst for hydrodehalogenation reactions of aliphatic fluorides and chlorides using triethylsilane as a reductant. In analogy to known homogeneous systems, full dehalogenation of organohalides is achieved with a predominant formation of Friedel-Crafts alkylation products in aromatic reaction media. Importantly, the herein described material is robust, tolerates elevated reaction temperatures and can be re-used, while reaching a turnover number (TON) of up to 5190. These features make it an attractive candidate for a sustainable disposal of halogenated pollutants by heterogeneous catalysis.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Catalysis Science &Technology
ISSN
2044-4753
e-ISSN
2044-4761
Volume of the periodical
14
Issue of the periodical within the volume
16
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
4458-4465
UT code for WoS article
001276127900001
EID of the result in the Scopus database
2-s2.0-85199541575