Decay of iron pentacarbonyl clusters upon interaction with heavy ions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F25%3A00604967" target="_blank" >RIV/61388955:_____/25:00604967 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/25:43931018
Result on the web
<a href="https://hdl.handle.net/11104/0362527" target="_blank" >https://hdl.handle.net/11104/0362527</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1088/1402-4896/ada205" target="_blank" >10.1088/1402-4896/ada205</a>
Alternative languages
Result language
angličtina
Original language name
Decay of iron pentacarbonyl clusters upon interaction with heavy ions
Original language description
The present work is a continuation of our studies with iron pentacarbonyl, a model organometallic precursor for Focused Ion Beam-Induced Deposition (FIBID). Interactions of He2+(16 keV), Ne+(6 keV), Ne4+(40 keV), Ar2+(12 keV) and Ar8+(64 keV) projectile ions with [Fe(CO)5]n clusters are studied using TOF mass spectrometry. The clusters represent an intermediate between the gas phase and the bulk environment and can be used as a proxy for the processes in complex environments such as e.g. the nanostructure deposition. The addition of environment in the present study results in the observation of fragments with high kinetic energies ejected from clusters, an overall reduction of the fragmentation, and observation of a range of fragments associated with C-O bond dissociation, not observed for isolated molecules. On the other hand, the high efficiency of the Ne+ projectile in fragmenting the Fe(CO)5 isolated molecule is also observed in clusters.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/EH22_008%2F0004558" target="_blank" >EH22_008/0004558: Advanced MUltiscaLe materials for key Enabling Technologies</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physica Scripta
ISSN
0031-8949
e-ISSN
1402-4896
Volume of the periodical
100
Issue of the periodical within the volume
2
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
025402
UT code for WoS article
001394235000001
EID of the result in the Scopus database
2-s2.0-85214801583