Reaction series not obeying the Hammett equation: conformational equilibria of substituted thiobenzanilides.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F02%3A57020088" target="_blank" >RIV/61388963:_____/02:57020088 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/02:00006540
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Reaction series not obeying the Hammett equation: conformational equilibria of substituted thiobenzanilides.
Original language description
The conformation of the C-N bond of 4,4'-disubstituted thiobenzanilides and the equilibrium Z,E were investigated by infrared spectroscopy and by the density functional theory. The substituent effects on log K are not governed by the Hammett equation. The most probable explanation is strong resonance effect and, a .pi.-.pi. interaction between the two substituted benzene rings.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F99%2F0030" target="_blank" >GA203/99/0030: The development of new antimycobacterially active substances using pharmacophore analysis and QSAR methods</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
New Journal of Chemistry
ISSN
1144-0546
e-ISSN
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Volume of the periodical
26
Issue of the periodical within the volume
N/A
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
861-866
UT code for WoS article
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EID of the result in the Scopus database
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