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Bulk versus Interfacial Aqueous Solvation of Dicarboxylate Dianions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F04%3A00100864" target="_blank" >RIV/61388963:_____/04:00100864 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Bulk versus Interfacial Aqueous Solvation of Dicarboxylate Dianions

  • Original language description

    Solvation of dicarboxylate dianions of varying length of the aliphatic chain in water clusters and in extended aqueous slabs was investigated using photoelectron spectroscopy and molecular dynamics simulations. Photoelectron spectra of hydrated succinate, adipate and tetradecandioic dianions with up to 20 water molecules were obtained. Even-odd effects were observed as a result of the alternate solvation mode of the two negative charges with increasing solvent numbers

  • Czech name

    Vnitřní versus povrchová vodní solvatace dikarboxylových dianiontů

  • Czech description

    Solvatace dikarboxylových dianiontů s různou délkou alifatického řetězce ve vodních klastrech a ve vodních vrstvách byla studována pomocí fotoelektronové spektroskopie a simulací molekulové dynamiky. Byla získána fotoelektronová spektra hydratovaného succinátu, adipátu a tetradekandiového dianiontu s až 20 molekulami vody. Byl pozorován efekt sudá-lichá jako výsledek alternující postupné solvatace dvou negativních nábojů

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LN00A032" target="_blank" >LN00A032: Structure and dynamics of complex molecular systems and biomolecules</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2004

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of the American Chemical Society

  • ISSN

    0002-7863

  • e-ISSN

  • Volume of the periodical

    126

  • Issue of the periodical within the volume

    37

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    11691-11698

  • UT code for WoS article

  • EID of the result in the Scopus database