Acidities of nitrous and nitric acids

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F05%3A00021123" target="_blank" >RIV/61388963:_____/05:00021123 - isvavai.cz</a>

Alternative codes found

RIV/60461373:22310/05:00020600

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Acidities of nitrous and nitric acids

Original language description

Energies of nitrous and nitric acid and their anions were calculated at the MP2(FC)/6-311++G(2d,2p) level. Their acidity was related to the acidity of hydroxylamine derivatives using isodesmic reactions. Molecules of HNO2 and HNO3 are strongly stabilizedbut their anions are stabilized still more. This stability is partly due to resonance and contribution of this effect wasroughly estimated.

Czech name

Acidita kyseliny dusité a dusičné

Czech description

Energie kyselin dusité a dusičná a jejich aniontú byly vypočteny na úrovni MP2(FC)/6-311++G(2d,2p) a acidita byla vztažena na aciditu hydroxylaminových derivátů pomocí isodesmických reakcí. Molekuly HNO2 a HNO3 jsou silně stabilizovány, ale jejich anionty jsou stabilizovány ještě vice. Stabilita je zčásti zpúsobena resonance; její podíl byl zhruba odhadnut.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/LN00A032" target="_blank" >LN00A032: Structure and dynamics of complex molecular systems and biomolecules</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2005

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

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Volume of the periodical

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Issue of the periodical within the volume

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Country of publishing house

DE - GERMANY

Number of pages

4

Pages from-to

1747-1750

UT code for WoS article

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EID of the result in the Scopus database

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