Remote Monitoring of a Multi-Component Liquid-Phase Organic Synthesis by Infrared Emission Spectroscopy: The Recovery of Pure Component Emissivities by Band-Target Entropy Minimization
Result description
Liquid-phase Diels-Alder cycloaddition between dimethyl acetylenedicarboxylate (DMAD) and cyclopentadiene (CP) to give dimethyl bicyclo[2.2.1]-2,5-heptadiene-2,3-dicarboxylate has been monitored by infrared emission spectroscopy. The pure component emission spectrum was retrieved from the reaction system using band-target entropy minimization (BTEM).
Keywords
infrared emission spectroscopyliquid phase reactionband-target entropy minimizationBTEMemittance
The result's identifiers
Result code in IS VaVaI
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Remote Monitoring of a Multi-Component Liquid-Phase Organic Synthesis by Infrared Emission Spectroscopy: The Recovery of Pure Component Emissivities by Band-Target Entropy Minimization
Original language description
Liquid-phase Diels-Alder cycloaddition between dimethyl acetylenedicarboxylate (DMAD) and cyclopentadiene (CP) to give dimethyl bicyclo[2.2.1]-2,5-heptadiene-2,3-dicarboxylate has been monitored by infrared emission spectroscopy. The pure component emission spectrum was retrieved from the reaction system using band-target entropy minimization (BTEM).
Czech name
Monitorování vícesložkové organicke reakce v kapalné fázi pomocí infračervené emisní spektroskopie: emisní hodnoty čistých komponent pomocí BTEM ("Band-Target Entropy Minimization")
Czech description
Diels-Alderova reakce v kapalné fázi mezi DMAD a cyklopentadienem, poskytující dimethyl bicyklo[2.2.1]-2,5-heptadien-2,3-dikarboxylát byla monitorována infračervenou emisní spektroskopií. Spektra jednotlivych component reakčního systému byla získána metodou BTEM ("Band-Target Entropy Minimization").
Classification
Type
Jx - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Applied Spectroscopy
ISSN
0003-7028
e-ISSN
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Volume of the periodical
61
Issue of the periodical within the volume
10
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
1057-1062
UT code for WoS article
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EID of the result in the Scopus database
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Basic information
Result type
Jx - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP
CC - Organic chemistry
Year of implementation
2007