Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F08%3A00314403" target="_blank" >RIV/61388963:_____/08:00314403 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins
Original language description
A tetrapodal pentadentate nitrogen ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) is used for the synthesis of the azido-iron(III) complex [(1)Fe(N3)]X2 (X =Br or PF6). Electrospray ionization affords the dication [(1)Fe(N3)]2+ as well as the dicationic nitrido-iron species [(1)FeN]2+.
Czech name
Aktivace C-H a N-H vazeb v plynné fázi vysoce valentním dikationtem nitridu kovu a {NH}-přenos k aktivaci olefinů
Czech description
Tetrapodální pentadentální dusíkatý ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) je používán pro syntézu komplexu azidu kovu(III) [(1)Fe(N3)]X2 (X =Br or PF6). Electrospray ionizace poskytuje dikationt [(1)Fe(N3)]2+ spolu s dikationickými sloučeninami nitridů kovu [(1)FeN]2+.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/KJB400550704" target="_blank" >KJB400550704: Intrinsic properties of redox-active molecules</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the American Chemical Society
ISSN
0002-7863
e-ISSN
—
Volume of the periodical
130
Issue of the periodical within the volume
13
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
—
UT code for WoS article
000254549000028
EID of the result in the Scopus database
—