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Application of capillary affinity electrophoresis and density functional theory to the investigation of benzo-18-crown-6-ether complex with ammonium cation

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F09%3A00332291" target="_blank" >RIV/61388963:_____/09:00332291 - isvavai.cz</a>

  • Alternative codes found

    RIV/61389013:_____/09:00332291

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Application of capillary affinity electrophoresis and density functional theory to the investigation of benzo-18-crown-6-ether complex with ammonium cation

  • Original language description

    Affinity capillary electrophoresis (ACE) and quantum mechanical density functional theory (DFT) have been employed for investigation of non-covalent interactions between macrocyclic ligand, benzo-18-crown-6-ether (B18C6), and ammonium cation, NH4+. The apparent binding constant (Kb) of the B18C6-NH4+ complex in a mixed binary hydro-organic solvent system, methanol-water (50/50, v/v), was determined by ACE, whereas the structural characteristics of B18C6-NH4+ complex were calculated and described by DFT.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Chromatography A

  • ISSN

    0021-9673

  • e-ISSN

  • Volume of the periodical

    1216

  • Issue of the periodical within the volume

    45

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    5

  • Pages from-to

  • UT code for WoS article

    000271408000041

  • EID of the result in the Scopus database