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Surface organization of aqueous MgCl2 and application to atmospheric marine aerosol chemistry

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F10%3A00342608" target="_blank" >RIV/61388963:_____/10:00342608 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Surface organization of aqueous MgCl2 and application to atmospheric marine aerosol chemistry

  • Original language description

    Inorganic salts in marine aerosols play an active role in atmospheric chemistry, particularly in coastal urban regions. The study of the interactions of these ions with water molecules at the aqueous surface helps to elucidate the role of inorganic cations and anions in atmospheric processes. We present surface vibrational sum frequency generation (VSFG) spectroscopic and molecular dynamics (MD) studies of aqueous MgCl-2 surfaces relevant to understanding marine aerosol. Spectroscopy results reveal thatthe disturbance of the hydrogen bonding environment of the air/aqueous solutions is dependent on the MgCl-2 concentration. At low concentrations (1 M) minor changes are observed. At concentrations above 1 M the hydrogen bonding environment is highly perturbed. The 2.1 M intermediate concentration solution shows the largest SFG response relative to the other solutions including concentrations as high as 4.7 M.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Proceedings of the National Academy of Sciences of the United States of America

  • ISSN

    0027-8424

  • e-ISSN

  • Volume of the periodical

    107

  • Issue of the periodical within the volume

    15

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000276642100013

  • EID of the result in the Scopus database