Enantioselective Allylation of Aldehydes Catalyzed by Diasteroisomeric Bis(tetrahydroisoquinoline) N, N'-Dioxides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F10%3A00353857" target="_blank" >RIV/61388963:_____/10:00353857 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Enantioselective Allylation of Aldehydes Catalyzed by Diasteroisomeric Bis(tetrahydroisoquinoline) N, N'-Dioxides
Original language description
The course of enantioselective allylation of aromatic and alpha, beta-unsaturated aldehydes with allyltrichlorosilane catalyzed by two diastereoisomeric (R,Rax,R)- and (R,Sax,R)-bis-1,1-[5,6,7,8-tetrahydro- 3-(tetrahydrofuran-2-yl)isoquinoline] N,N-dioxides was influenced by the solvent. The (R,Sax,R) catalyst efficiently promoted the reaction in THF with enantioselectivity up to 96%. On the other hand, the allylation of aromatic aldehydes in the presence of the (R,Rax,R) catalyst proceeded only in MeCN(up to 67%ee). The allylation of alpha, beta- unsaturated aldehydes proceeded only in dichloromethane (enantioselectivity up to 68%).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Organic Chemistry
ISSN
1434-193X
e-ISSN
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Volume of the periodical
-
Issue of the periodical within the volume
36
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
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UT code for WoS article
000285311000021
EID of the result in the Scopus database
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