Energy partitioning in single-electron transfer events between gaseous dications and their neutral counterparts

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F12%3A00379220" target="_blank" >RIV/61388963:_____/12:00379220 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1255/ejms.1161" target="_blank" >http://dx.doi.org/10.1255/ejms.1161</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1255/ejms.1161" target="_blank" >10.1255/ejms.1161</a>

Result language
angličtina
Original language name
Energy partitioning in single-electron transfer events between gaseous dications and their neutral counterparts
Original language description
Electron-transfer reactions between hydrocarbon dications with neutral hydrocarbons lead to an unequal deposition of the excess energy from the reaction in the pair of monocations formed. The initial observation of this phenomenon was explained by the different states accessible upon single-electron capture by a dication compared to single-electron ejection from a neutral compound. Alternatively, however, isomeric structures of the dicationic species, pronounced Franck-Condon effects, as well as excessenergy in the dicationic precursors could cause the asymmetric energy partitioning in such dication/neutral collisions. Here, the investigation of this phenomenon in an interdisciplinary cooperation is described, shedding light not only upon a possible solution of the problem at hand, but also providing an example for the synergistic benefits of international research networks applying complementary approaches.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F09%2F1223" target="_blank" >GA203/09/1223: Bond-forming reactions of hydrocarbon dications</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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