Synthesis of N-substituted a,a-difluoro-b-aminophosphonates by addition of diethyl lithiodifluoromethylphosphonate to imines

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F12%3A00379965" target="_blank" >RIV/61388963:_____/12:00379965 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jfluchem.2012.06.004" target="_blank" >http://dx.doi.org/10.1016/j.jfluchem.2012.06.004</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jfluchem.2012.06.004" target="_blank" >10.1016/j.jfluchem.2012.06.004</a>

Result language
angličtina
Original language name
Synthesis of N-substituted a,a-difluoro-b-aminophosphonates by addition of diethyl lithiodifluoromethylphosphonate to imines
Original language description
Addition of diethyl lithiodifluoromethylphosphonate to N-substituted imines provides N-substituted alpha,alpha-difluoro-beta-aminophosphonates. N-Alkyl, aryl, or Boc substituted aldimines give good to high yields in these reactions, while in ketimine series, only activated N-(2,2,2-trifluoro-1-phenylethylidene)aniline showed high reactivity.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GP203%2F08%2FP310" target="_blank" >GP203/08/P310: Nucleophilic introduction of fluorinated groups using organo-phosphorus compounds</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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