Isoflurane as a solvent for electrochemistry. Electrooxidation study of icosahedral carborane anions in four different solvents

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F13%3A00386134" target="_blank" >RIV/61388963:_____/13:00386134 - isvavai.cz</a>

Alternative codes found

RIV/61388955:_____/13:00386134

Result on the web

<a href="http://dx.doi.org/10.1016/j.jelechem.2012.10.002" target="_blank" >http://dx.doi.org/10.1016/j.jelechem.2012.10.002</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jelechem.2012.10.002" target="_blank" >10.1016/j.jelechem.2012.10.002</a>

Result language

angličtina

Original language name

Isoflurane as a solvent for electrochemistry. Electrooxidation study of icosahedral carborane anions in four different solvents

Original language description

Voltammetric studies of icosahedral carborane anions View the MathML source (1), View the MathML source (2), View the MathML source (3), and View the MathML source (4) are reported in isoflurane (1-chloro-2,2,2-trifluoroethyl difluoromethyl ether) and inthree other solvents with different polarity (liquid SO2, acetonitrile, dichloromethane). They demonstrate the first use of isoflurane as a non-polar electrochemical solvent. The anions 1, 2 and 3 show reversible one-electron oxidations in all four solvents, whereas the oxidation of 4 is irreversible even at high scan rates. The measured half-wave potentials (E1/2) show a remarkable variation in the four different solvents. The E1/2 values are discussed in terms of specific solvation of the anions. Theexperimental results correlate fairly well with density functional theory (DFT) calculations.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Electroanalytical Chemistry

ISSN

1572-6657

e-ISSN

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Volume of the periodical

689

Issue of the periodical within the volume

JAN 2013

Country of publishing house

CH - SWITZERLAND

Number of pages

5

Pages from-to

257-261

UT code for WoS article

000317161300036

EID of the result in the Scopus database

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