All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

A Hyphenation of Stripping Voltammetry with Electrospray Ionization Mass Spectrometry; an Effect of Sodium Perchlorate on Ferrocene Oxidation

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F13%3A00393001" target="_blank" >RIV/61388963:_____/13:00393001 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388955:_____/13:00393001 RIV/60460709:41210/13:59903

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    A Hyphenation of Stripping Voltammetry with Electrospray Ionization Mass Spectrometry; an Effect of Sodium Perchlorate on Ferrocene Oxidation

  • Original language description

    The coupling of electrospray ionization mass spectrometry (ESI-MS) with an electrochemical (EC) method is a promising technique applicable in electrochemical reaction studies as well as in other analytical fields. The connection of two-electrodes flowingEC cell prior ESI-MS is provided and tested on ferrocene/ferricene system. The base electrolyte used (a mixture of NaClO4 and HClO4) causes particular oxidation of ferrocene to ferricene. Consequently, in ESI-MS spectrum are observed two charged ferricene/ferrocene species: protonated ferrocene (Cp2Fe(II)H)(+) and ferricene (Cp2Fe(III))(+). In the on-line connection of EC with ESI-MS the ferricene species is electrochemically reduced (in accumulation step of differential pulse anodic stripping voltammetry via insertion of negative potential) to ferrocene species, which is detected as (Cp2Fe(II)H)(+) using ESI-MS. The yield of electrochemical reduction of ferricene to ferrocene is almost 30 %, whereas the inserted potential is -1000 mV.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP206%2F11%2F1638" target="_blank" >GAP206/11/1638: Novel electrochemical sensors and sensing techniques for the analysis of nucleic acids structure and interactions</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    International Journal of Electrochemical Science

  • ISSN

    1452-3981

  • e-ISSN

  • Volume of the periodical

    8

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    CS - SERBIA AND MONTENEGRO

  • Number of pages

    12

  • Pages from-to

    1623-1634

  • UT code for WoS article

    000316565800007

  • EID of the result in the Scopus database