Unexpectedly Small Effect of the DNA Environment on Vertical Ionization Energies of Aqueous Nucleobases

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F13%3A00421016" target="_blank" >RIV/61388963:_____/13:00421016 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/13:43895773
Result on the web
<a href="http://dx.doi.org/10.1021/jz402106h" target="_blank" >http://dx.doi.org/10.1021/jz402106h</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jz402106h" target="_blank" >10.1021/jz402106h</a>

Result language
angličtina
Original language name
Unexpectedly Small Effect of the DNA Environment on Vertical Ionization Energies of Aqueous Nucleobases
Original language description
By a combination of ab initio calculations and photoelectron spectroscopy, we demonstrate that the DNA surrounding has only a negligible effect on ionization energies of nucleobases in the native aqueous environment. The aqueous solution thus effectivelyscreens the sugar-phosphate backbone and the neighboring nucleobases. Consequently, vertical ionization potentials of nucleobases in aqueous DNA can be reliably derived from the corresponding values for its building blocks in water, that is, aqueous nucleobases, nucleosides, or nucleotides.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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