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Synthetic routes contaminate graphene materials with a whole spectrum of unanticipated metallic elements

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F14%3A00433715" target="_blank" >RIV/61388963:_____/14:00433715 - isvavai.cz</a>

  • Alternative codes found

    RIV/61389005:_____/14:00433715 RIV/60461373:22310/14:43897464

  • Result on the web

    <a href="http://dx.doi.org/10.1073/pnas.1413389111" target="_blank" >http://dx.doi.org/10.1073/pnas.1413389111</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1073/pnas.1413389111" target="_blank" >10.1073/pnas.1413389111</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthetic routes contaminate graphene materials with a whole spectrum of unanticipated metallic elements

  • Original language description

    he synthesis of graphene materials is typically carried out by oxidizing graphite to graphite oxide followed by a reduction process. Numerous methods exist for both the oxidation and reduction steps, which causes unpredictable contamination from metallicimpurities into the final material. These impurities are known to have considerable impact on the properties of graphene materials. We synthesized several reduced graphene oxides from extremely pure graphite using several popular oxidation and reductionmethods and tracked the concentrations of metallic impurities at each stage of synthesis. We show that different combinations of oxidation and reduction introduce varying types as well as amounts of metallic elements into the graphene materials, and their origin can be traced to impurities within the chemical reagents used during synthesis. These metallic impurities are able to alter the graphene materials' electrochemical properties significantly and have wide-reaching implications on

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Proceedings of the National Academy of Sciences of the United States of America

  • ISSN

    0027-8424

  • e-ISSN

  • Volume of the periodical

    111

  • Issue of the periodical within the volume

    38

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

    13774-13779

  • UT code for WoS article

    000341988200035

  • EID of the result in the Scopus database