Observation of Paramagnetic Raman Optical Activity of Nitrogen Dioxide

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F14%3A00434058" target="_blank" >RIV/61388963:_____/14:00434058 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1002/anie.201403887" target="_blank" >http://dx.doi.org/10.1002/anie.201403887</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/anie.201403887" target="_blank" >10.1002/anie.201403887</a>

Result language

angličtina

Original language name

Observation of Paramagnetic Raman Optical Activity of Nitrogen Dioxide

Original language description

Raman optical activity (ROA) detects the intensity difference between right and left circularly polarized scattered light, and thus brings about enhanced information about the molecules under investigation. The difference is quite small and the techniqueis mostly constrained to the condensed phase. For NO2 in the presence of a static magnetic field, however, the ROA signal with high ROA/Raman intensity ratio was observed. The signal is so strong owing to molecular paramagnetism and a pre- resonance signal enhancement. The spectral shape was explained on the basis of the Fermi golden rule and rotational wave functions expanded to a spherical top basis. The results indicate that the technique can be immediately used to obtain information about molecularproperties, such as polarizability components. It also has a potential to detect other paramagnetic gases and discriminate among them.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Angewandte Chemie - International Edition

ISSN

1433-7851

e-ISSN

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Volume of the periodical

53

Issue of the periodical within the volume

35

Country of publishing house

DE - GERMANY

Number of pages

4

Pages from-to

9236-9239

UT code for WoS article

000342676100019

EID of the result in the Scopus database

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