LiquidLiquid Equilibria in Ternary Systems of Hexafluoroisopropanol plus Perfluorocarbon plus Water or Methanol at 298.15 K
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F14%3A00435742" target="_blank" >RIV/61388963:_____/14:00435742 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/14:43897761
Result on the web
<a href="http://dx.doi.org/10.1021/je500455u" target="_blank" >http://dx.doi.org/10.1021/je500455u</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/je500455u" target="_blank" >10.1021/je500455u</a>
Alternative languages
Result language
angličtina
Original language name
LiquidLiquid Equilibria in Ternary Systems of Hexafluoroisopropanol plus Perfluorocarbon plus Water or Methanol at 298.15 K
Original language description
Liquid-liquid equilibrium data for ternary systems hexafluoroisopropanol + perfluorocarbon (namely perfluoro(n-hexane) or perfluoro(methylcyclohexane)) + water or methanol were determined at 298.15 K. Water, methanol, and other polar solvents exhibit very low miscibility with perfluorocarbons. In contrast, hexafluoroisopropanol is fully miscible with water, methanol, and perfluorocarbons. Consequently, the determined ternary liquidliquid equilibrium diagrams possess only one heterogeneous binary subsystem. They are of the type 1. Due to specific properties of perfluorocarbons, a special procedure for determination of the liquidliquid equilibrium in the studied systems was developed. The ternary liquidliquid equilibrium diagrams were found to be almostidentical for perfluoro(n-hexane) and perfluoro(methylcyclohexane) showing that the structure of perfluorocarbon component has minimal influence on the miscibility behavior.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical and Engineering Data
ISSN
0021-9568
e-ISSN
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Volume of the periodical
59
Issue of the periodical within the volume
11
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
3510-3516
UT code for WoS article
000344977600025
EID of the result in the Scopus database
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