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Combining UV photodissociation with electron transfer for peptide structure analysis

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F15%3A00443979" target="_blank" >RIV/61388963:_____/15:00443979 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989592:15310/15:73576169

  • Result on the web

    <a href="http://dx.doi.org/10.1002/jms.3551" target="_blank" >http://dx.doi.org/10.1002/jms.3551</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/jms.3551" target="_blank" >10.1002/jms.3551</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Combining UV photodissociation with electron transfer for peptide structure analysis

  • Original language description

    The combination of near-UV photodissociation with electron transfer and collisional activation provides a new tool for structure investigation of isolated peptide ions and reactive intermediates. Two new types of pulse experiments are reported. In the first one called UV/Vis photodissociation-electron transfer dissociation (UVPD-ETD), diazirine-labeled peptide ions are shown to undergo photodissociation in the gas phase to form new covalent bonds, guided by the ion conformation, and the products are analyzed by electron transfer dissociation. In the second experiment, called ETD-UVPD wherein synthetic labels are not necessary, electron transfer forms new cation-peptide radical chromophores that absorb at 355nm and undergo specific backbone photodissociation reactions. The new method is applied to distinguish isomeric ions produced by ETD of arginine containing peptides.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CE - Biochemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Mass Spectrometry

  • ISSN

    1076-5174

  • e-ISSN

  • Volume of the periodical

    50

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    6

  • Pages from-to

    470-475

  • UT code for WoS article

    000351682100006

  • EID of the result in the Scopus database

    2-s2.0-84924584287