Synthesis and reactivity of aliphatic sulfur pentafluorides from substituted (pentafluorosulfanyl)benzenes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F16%3A00458583" target="_blank" >RIV/61388963:_____/16:00458583 - isvavai.cz</a>
Result on the web
<a href="http://www.beilstein-journals.org/bjoc/single/articleFullText.htm?publicId=1860-5397-12-12" target="_blank" >http://www.beilstein-journals.org/bjoc/single/articleFullText.htm?publicId=1860-5397-12-12</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3762/bjoc.12.12" target="_blank" >10.3762/bjoc.12.12</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and reactivity of aliphatic sulfur pentafluorides from substituted (pentafluorosulfanyl)benzenes
Original language description
Oxidation of 3- and 4-pentafluorosulfanyl-substituted anisoles and phenols with hydrogen peroxide and sulfuric acid provided a mixture of SF5-substituted muconolactone, maleic, and succinic acids. A plausible mechanism for the formation of the aliphatic SF5 compounds was presented and their chemical reactivity was investigated. SF5-substituted para-benzoquinone was synthesized; its oxidation led to an improved yield of 2-(pentafluorosulfanyl)maleic acid. The reaction of SF5-substituted maleic anhydride and para-benzoquinone with cyclopentadiene afforded the Diels-Alder adducts. Decomposition of 3-(pentafluorosulfanyl)muconolactone in acidic, neutral and basic aqueous media was investigated and the decarboxylation of 2-(pentafluorosulfanyl)maleic acid provided 3-(pentafluorosulfanyl)acrylic acid.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Beilstein Journal of Organic Chemistry
ISSN
1860-5397
e-ISSN
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Volume of the periodical
12
Issue of the periodical within the volume
Jan 20
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
110-116
UT code for WoS article
000368474300001
EID of the result in the Scopus database
2-s2.0-84962206122