Synthesis and nucleophilic aromatic substitution of 3-fluoro-5-nitro-1-(pentafluorosulfanyl)benzene

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F16%3A00458729" target="_blank" >RIV/61388963:_____/16:00458729 - isvavai.cz</a>
Result on the web
<a href="http://www.beilstein-journals.org/bjoc/single/articleFullText.htm?publicId=1860-5397-12-21" target="_blank" >http://www.beilstein-journals.org/bjoc/single/articleFullText.htm?publicId=1860-5397-12-21</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3762/bjoc.12.21" target="_blank" >10.3762/bjoc.12.21</a>

Result language
angličtina
Original language name
Synthesis and nucleophilic aromatic substitution of 3-fluoro-5-nitro-1-(pentafluorosulfanyl)benzene
Original language description
3-Fluoro-5-nitro-1-(pentafluorosulfanyl) benzene was prepared by three different ways: as a byproduct of direct fluorination of 1,2-bis-(3-nitrophenyl) disulfane, by direct fluorination of 4-nitro-1-(pentafluorosulfanyl) benzene, and by fluorodenitration of 3,5-dinitro-1-(pentafluorosulfanyl) benzene. The title compound was subjected to a nucleophilic aromatic substitution of the fluorine atom with oxygen, sulfur and nitrogen nucleophiles affording novel (pentafluorosulfanyl) benzenes with 3,5-disubstitution pattern. Vicarious nucleophilic substitution of the title compound with carbon, oxygen, and nitrogen nucleophiles provided 3-fluoro-5-nitro-1-(pentafluorosulfanyl) benzenes substituted in position four.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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