Low-Temperature PM IRRAS of a Monolayer on Au: Spectra of C18D37SH

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F17%3A00477128" target="_blank" >RIV/61388963:_____/17:00477128 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/17:43913388
Result on the web
<a href="http://dx.doi.org/10.1021/acs.langmuir.7b00293" target="_blank" >http://dx.doi.org/10.1021/acs.langmuir.7b00293</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.langmuir.7b00293" target="_blank" >10.1021/acs.langmuir.7b00293</a>

Result language
angličtina
Original language name
Low-Temperature PM IRRAS of a Monolayer on Au: Spectra of C18D37SH
Original language description
We describe an experimental setup suitable for the measurement of photomodulated IR reflection/absorption spectra of monolayers on a flat gold substrate at temperatures from room to 14 K. Results obtained for a monolayer of C18D37SH on gold are shown and compared with IR spectra of C18D37SH in a KBr pellet at these temperatures. Band widths are reduced by only similar to 40%. Upon cooling below 100-150 K, the frequencies and intensities of v(as)(CD3) and v(as)(CD2) bands in the C-D stretching region in both types of spectra undergo reversible changes attributed to disappearance of gauche defects by analogy to the behavior of previously studied chains.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/GA14-02337S" target="_blank" >GA14-02337S: New Functionalization of Gold Surfaces</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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