Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F17%3A00486998" target="_blank" >RIV/61388963:_____/17:00486998 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s11224-016-0854-2" target="_blank" >http://dx.doi.org/10.1007/s11224-016-0854-2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11224-016-0854-2" target="_blank" >10.1007/s11224-016-0854-2</a>
Alternative languages
Result language
angličtina
Original language name
Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group
Original language description
Nine pentafluorosulfuranyl (SF5)-containing aromatic compounds have been characterized crystallographically. The SF5 group has an umbrella geometry, and the sulfur atom in the SF5 group is in an approximately octahedral coordination environment. All S-F bond lengths [1.572(3)-1.618(3) ] are very similar, and the C-S-F-ax bond angles [178.94(14)-180A degrees] are very close to each other. The angle of two adjacent F-eq is approximately 90A degrees. The intramolecular and intermolecular interactions such as C-aryl-H center dot center dot center dot F-eq, C-aryl-H center dot center dot center dot O/N/F/Cl interactions, and pi-stacking interactions play a very important role in their three-dimensional packing frameworks.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Structural Chemistry
ISSN
1040-0400
e-ISSN
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Volume of the periodical
28
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
723-733
UT code for WoS article
000400574100018
EID of the result in the Scopus database
2-s2.0-84990856298