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Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F17%3A00486998" target="_blank" >RIV/61388963:_____/17:00486998 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s11224-016-0854-2" target="_blank" >http://dx.doi.org/10.1007/s11224-016-0854-2</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11224-016-0854-2" target="_blank" >10.1007/s11224-016-0854-2</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group

  • Original language description

    Nine pentafluorosulfuranyl (SF5)-containing aromatic compounds have been characterized crystallographically. The SF5 group has an umbrella geometry, and the sulfur atom in the SF5 group is in an approximately octahedral coordination environment. All S-F bond lengths [1.572(3)-1.618(3) ] are very similar, and the C-S-F-ax bond angles [178.94(14)-180A degrees] are very close to each other. The angle of two adjacent F-eq is approximately 90A degrees. The intramolecular and intermolecular interactions such as C-aryl-H center dot center dot center dot F-eq, C-aryl-H center dot center dot center dot O/N/F/Cl interactions, and pi-stacking interactions play a very important role in their three-dimensional packing frameworks.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Structural Chemistry

  • ISSN

    1040-0400

  • e-ISSN

  • Volume of the periodical

    28

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    723-733

  • UT code for WoS article

    000400574100018

  • EID of the result in the Scopus database

    2-s2.0-84990856298