Dutch Resolution of a configurationally stable [5]helquat
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00489617" target="_blank" >RIV/61388963:_____/18:00489617 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/18:10374487
Result on the web
<a href="http://dx.doi.org/10.1002/chir.22789" target="_blank" >http://dx.doi.org/10.1002/chir.22789</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chir.22789" target="_blank" >10.1002/chir.22789</a>
Alternative languages
Result language
angličtina
Original language name
Dutch Resolution of a configurationally stable [5]helquat
Original language description
Synthesis and nontrivial optical resolution of a helicene-like dication, helquat 1, has been accomplished. Starting with gram scale of the racemic helquat 1 sample, Dutch Resolution using family of 3 tartrate anions was key to achieve successful separation of M and P helical enantiomers of 1. Hundreds of milligrams of each enantiomer of this configurationally stable C-2-symmetric helquat have been obtained. Racemization barrier of 1 has been determined. To our knowledge this is the first report on Dutch Resolution performed with a helicene-like compound. Moreover, there are no literature precedents for Dutch Resolution of chiral quaternary ammonium cations.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chirality
ISSN
0899-0042
e-ISSN
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Volume of the periodical
30
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
254-260
UT code for WoS article
000424886400005
EID of the result in the Scopus database
2-s2.0-85039803621