A rhodium-catalyzed transannulation of N-(per)fluoroalkyl-1,2,3-triazoles under microwave conditions - a general route to N-(per)fluoroalkyl-substituted five-membered heterocycles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00489836" target="_blank" >RIV/61388963:_____/18:00489836 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/18:10374849
Result on the web
<a href="http://dx.doi.org/10.1039/c8cc01446a" target="_blank" >http://dx.doi.org/10.1039/c8cc01446a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c8cc01446a" target="_blank" >10.1039/c8cc01446a</a>
Alternative languages
Result language
angličtina
Original language name
A rhodium-catalyzed transannulation of N-(per)fluoroalkyl-1,2,3-triazoles under microwave conditions - a general route to N-(per)fluoroalkyl-substituted five-membered heterocycles
Original language description
A rhodium-catalyzed transannulation via ring-opening of N-(per)fluoroalkyl-substituted 1,2,3-triazoles followed by cycloaddition with different nitriles, enol ethers, isocyanates and silyl ketene acetals under microwave heating provided a highly efficient route to previously unreported N-(per) fluoroalkyl-substituted imidazoles, pyrroles, imidazolones and pyrrolones, respectively. These reactions were found to be applicable to the synthesis of a variety of 5-membered heterocycles bearing different (per) fluoroalkyl substituents aswell as both electron-donating and electron-withdrawing groups attached to the heterocyclic core.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Communications
ISSN
1359-7345
e-ISSN
—
Volume of the periodical
54
Issue of the periodical within the volume
26
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
3258-3261
UT code for WoS article
000428553500015
EID of the result in the Scopus database
2-s2.0-85044670257