Synthesis of novel dithiocarbamates and xanthates using dialkyl azodicarboxylates: S-N bond formation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00490314" target="_blank" >RIV/61388963:_____/18:00490314 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.tet.2018.02.049" target="_blank" >http://dx.doi.org/10.1016/j.tet.2018.02.049</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tet.2018.02.049" target="_blank" >10.1016/j.tet.2018.02.049</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis of novel dithiocarbamates and xanthates using dialkyl azodicarboxylates: S-N bond formation
Original language description
A one-pot three-component route for the synthesis of a novel category of dithiocarbamates or xanthates is developed by a reaction of in-situ generated dithiocarbamic acids or xanthates with dialkyl azodicarboxylates under mild and catalyst-free conditions. The reaction is characterized by a wide scope, high efficiency and straightforward isolation protocol. The synthetic utility of the dithiocarbamates and xanthates was demonstrated on the preparation of symmetrical and unsymmetrical thioureas, isothiocyanates, and thiocarbamates.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Tetrahedron
ISSN
0040-4020
e-ISSN
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Volume of the periodical
74
Issue of the periodical within the volume
15
Country of publishing house
GB - UNITED KINGDOM
Number of pages
9
Pages from-to
1850-1858
UT code for WoS article
000430028400015
EID of the result in the Scopus database
2-s2.0-85042609868