Stereocontrolled Photoinduced Electron Transfer in Metal-Fullerene Hybrids
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00493444" target="_blank" >RIV/61388963:_____/18:00493444 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/chem.201802381" target="_blank" >http://dx.doi.org/10.1002/chem.201802381</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201802381" target="_blank" >10.1002/chem.201802381</a>
Alternative languages
Result language
angličtina
Original language name
Stereocontrolled Photoinduced Electron Transfer in Metal-Fullerene Hybrids
Original language description
Photoinduced electron transfer in transition-metal complexes linked to a fullerene moiety is of increasing interest. Recently, several stereoisomers of an Ir-complex exhibiting configurational stability at metal center, which does not undergo epimerization have been synthesized (Angew. Chem. Int. Ed. 2017, 56, 2136). The presence of multiple electron donor and acceptor sites located at opposite ends with respect to the metallic center creates the prerequisites for the formation of entirely different charge transfer (CT) states. Here we report the results of quantum mechanical calculations and detailed analysis of excited-state properties for all stereoisomers of the junction. We found that the stereoisomers demonstrate clearly different CT properties by photoexcitation. The found photo-stereospecific effects can be used to design new hybrids with a different type of photoinduced CT state, exhibiting dissimilar activity in photocatalysis.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
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Volume of the periodical
24
Issue of the periodical within the volume
49
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
13020-13025
UT code for WoS article
000443382500034
EID of the result in the Scopus database
2-s2.0-85051066401