Pt...Pt interaction triggered tuning of circularly polarized luminescence activity in chiral dinuclear platinum(II) complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00494215" target="_blank" >RIV/61388963:_____/18:00494215 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlehtml/2018/dt/c8dt02277a" target="_blank" >https://pubs.rsc.org/en/content/articlehtml/2018/dt/c8dt02277a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c8dt02277a" target="_blank" >10.1039/c8dt02277a</a>
Alternative languages
Result language
angličtina
Original language name
Pt...Pt interaction triggered tuning of circularly polarized luminescence activity in chiral dinuclear platinum(II) complexes
Original language description
Circularly polarized luminescence (CPL) activity switched by Pt...Pt interaction is disclosed in two couples of dinuclear Pt(II) complex enantiomers. Upon varying the length of the bridging ligand, intramolecular metal-metal interaction manipulation is achieved as evidenced from crystal structures. Complex (-)-1 exhibiting strong Pt...Pt interaction displays red phosphorescence with a maximum peak at 638 nm, while complex (-)-2 exhibiting weak Pt...Pt interaction displays green phosphorescence with a maximum peak at 530 nm. The observed CPL was opposite in sign for the two complexes. TD-DFT simulations further confirmed the influence of the Pt...Pt distance on the difference in the electronic optical activities.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GJ16-08764Y" target="_blank" >GJ16-08764Y: Synthesis and Spectroscopic Characterization of Lanthanide Complexes as Chiral Probes in Structural Studies</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton Transactions
ISSN
1477-9226
e-ISSN
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Volume of the periodical
47
Issue of the periodical within the volume
30
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
10179-10186
UT code for WoS article
000444201700026
EID of the result in the Scopus database
2-s2.0-85050978370