Molecular Rods: Facile Desymmetrization of 1,4-Diethynylbicyclo[2.2.2]octane

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00495595" target="_blank" >RIV/61388963:_____/18:00495595 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/18:10381912
Result on the web
<a href="http://dx.doi.org/10.1002/ejoc.201800507" target="_blank" >http://dx.doi.org/10.1002/ejoc.201800507</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejoc.201800507" target="_blank" >10.1002/ejoc.201800507</a>

Result language
angličtina
Original language name
Molecular Rods: Facile Desymmetrization of 1,4-Diethynylbicyclo[2.2.2]octane
Original language description
We report a facile desymmetrization of 1,4-diethynylbicyclo[2.2.2]octane. One of the acetylene termini was protected by TMS and the desired product was purified by sublimation. It is stable but reactive, as shown by the synthesis of a complex pyridine-terminated molecular rod containing both a bicyclo[1.1.1]pentane and a bicyclo[2.2.2]octane cage. Six crystal structures of key intermediates are presented.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/7AMB16FR038" target="_blank" >7AMB16FR038: Functional materials based on bicyclo[1.1.1]pentan rotors: organization and dynamics</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)