Dihydrogen contacts observed by through-space indirect NMR coupling

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00496365" target="_blank" >RIV/61388963:_____/18:00496365 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlehtml/2018/sc/c8sc02859a" target="_blank" >https://pubs.rsc.org/en/content/articlehtml/2018/sc/c8sc02859a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c8sc02859a" target="_blank" >10.1039/c8sc02859a</a>

Result language
angličtina
Original language name
Dihydrogen contacts observed by through-space indirect NMR coupling
Original language description
“Through-space” indirect spin-spin couplings between hydrogen atoms formally separated by up to 18 covalent bonds have been detected by NMR experiments in model helical molecules. It is demonstrated that this coupling can provide crucial structural information on the molecular conformation in solution. The coupling pathways have been visualised and analysed by computational methods. The conformational dependence of the coupling is explained in terms of orbital interactions.
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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