Regular Two-Dimensional Arrays of Surface-Mounted Molecular Switches: Switching Monitored by UV–vis and NMR Spectroscopy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F20%3A00525620" target="_blank" >RIV/61388963:_____/20:00525620 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/20:10412397
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/jacs.0c01753" target="_blank" >https://pubs.acs.org/doi/10.1021/jacs.0c01753</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jacs.0c01753" target="_blank" >10.1021/jacs.0c01753</a>
Alternative languages
Result language
angličtina
Original language name
Regular Two-Dimensional Arrays of Surface-Mounted Molecular Switches: Switching Monitored by UV–vis and NMR Spectroscopy
Original language description
Using solid-state 15N NMR spectroscopy, the cis/trans isomerization in a two-dimensional (2-D) array of surface-mounted azobenzene-based switches was detected for the first time. In order to achieve this, a new class of rod-shaped molecular switches, suitable for formation of 2-D regular arrays on large facets of tris(o-phenylenedioxy)cyclotriphosphazene (TPP) nanocrystals, was synthesized. A mechanochemical approach was used to prepare corresponding host–guest surface inclusions in a TPP matrix. Comparison of thermal steps in solution and supramolecular surface inclusions revealed that switching of individual molecules is not compromised by the close proximity of neighbors.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the American Chemical Society
ISSN
0002-7863
e-ISSN
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Volume of the periodical
142
Issue of the periodical within the volume
20
Country of publishing house
US - UNITED STATES
Number of pages
15
Pages from-to
9337-9351
UT code for WoS article
000537415600030
EID of the result in the Scopus database
2-s2.0-85086506983