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A multistimuli responsive heteroleptic iridium(iii) complex: role of hydrogen bonding in probing solvent, pH and bovine serum albumin (BSA)

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F20%3A00525623" target="_blank" >RIV/61388963:_____/20:00525623 - isvavai.cz</a>

  • Result on the web

    <a href="https://pubs.rsc.org/en/content/articlelanding/2020/TC/C9TC07050H#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2020/TC/C9TC07050H#!divAbstract</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c9tc07050h" target="_blank" >10.1039/c9tc07050h</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    A multistimuli responsive heteroleptic iridium(iii) complex: role of hydrogen bonding in probing solvent, pH and bovine serum albumin (BSA)

  • Original language description

    This article focuses on the vital role of hydrogen bonding to explain some unusual photophysical behaviors of an ‘Aggregation-induced emission’ (AIE) active Iridium(III) complex. The preponderance of hydrogen bonding leads to the complex's multifunctional character, viz., sensing ability of base and protein (BSA), pH probing, and solvatochromism. Depending on the hydrogen bonding capacity of the solvents, the emission properties of the complex are changed, i.e., green emission in non-polar solvents, yellowish-green emission in a chlorinated solvent, bright yellow emission in a polar aprotic solvent and weak yellow emission in polar protic solvent. A robust green emission was obtained with the addition of BSA into a solution of 1. The sensitivity of the complex to BSA was measured to be 9.3 pM. The mechanisms in all these cases have been explored based on control experiments and computational calculations/studies (DFT, TD-DFT, Docking).

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Materials Chemistry C

  • ISSN

    2050-7526

  • e-ISSN

  • Volume of the periodical

    8

  • Issue of the periodical within the volume

    19

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    10

  • Pages from-to

    6605-6614

  • UT code for WoS article

    000536880000029

  • EID of the result in the Scopus database

    2-s2.0-85085922349