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Tandem Michael addition/elimination novel reactivity of pyridinium ylides in reaction with electron-deficient alkenes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F22%3A00560624" target="_blank" >RIV/61388963:_____/22:00560624 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1039/D2QO00911K" target="_blank" >https://doi.org/10.1039/D2QO00911K</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d2qo00911k" target="_blank" >10.1039/d2qo00911k</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Tandem Michael addition/elimination novel reactivity of pyridinium ylides in reaction with electron-deficient alkenes

  • Original language description

    Novel reactivity of pyridinium ylides in reaction with annulated 4-oxothiazolidin-5-ylidenes as electron-deficient alkenes involving a cascade Michael addition/elimination process is described. The method provides a broad variety of functionalized products available from dipolarophiles with different substituents within the heterocyclic system as well as pyridinium salts with different electron-withdrawing groups (EWG = CO2R, COPh, COMe, CN) in mild conditions with good to excellent yields.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Organic Chemistry Frontiers

  • ISSN

    2052-4129

  • e-ISSN

    2052-4129

  • Volume of the periodical

    9

  • Issue of the periodical within the volume

    18

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    4998-5004

  • UT code for WoS article

    000839576200001

  • EID of the result in the Scopus database

    2-s2.0-85136296536