N-Acyl-1,2,3-triazoles – key intermediates in denitrogenative transformations

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F23%3A00573759" target="_blank" >RIV/61388963:_____/23:00573759 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1039/D3CC00987D" target="_blank" >https://doi.org/10.1039/D3CC00987D</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/D3CC00987D" target="_blank" >10.1039/D3CC00987D</a>

Result language
angličtina
Original language name
N-Acyl-1,2,3-triazoles – key intermediates in denitrogenative transformations
Original language description
Elusive N-acyl-1,2,3-triazoles formed by direct acylation of NH-1,2,3-triazoles were isolated and fully characterized, including X-ray crystallography. A preference for the formation of thermodynamic N2 isomers was established. Direct evidence of interconversion between N1- and N2-acyltriazoles confirmed their value in denitrogenative transformations. Efficient synthesis of enamido triflates from NH-triazoles via the intermediacy of N2-acyl-1,2,3-triazoles was developed.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/GA23-04659S" target="_blank" >GA23-04659S: Utilization of organic fluorinated azides for the synthesis of unusual nitrogen heterocycles</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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