Cu(III) Trifluoromethyl Complexes with 1,3-Diketonate Ligands and Their Versatile Reactivity in C–H Trifluoromethylation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F23%3A00573761" target="_blank" >RIV/61388963:_____/23:00573761 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1002/adsc.202300695" target="_blank" >https://doi.org/10.1002/adsc.202300695</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adsc.202300695" target="_blank" >10.1002/adsc.202300695</a>
Alternative languages
Result language
angličtina
Original language name
Cu(III) Trifluoromethyl Complexes with 1,3-Diketonate Ligands and Their Versatile Reactivity in C–H Trifluoromethylation
Original language description
High-valent Cu(III) trifluoromethyl complexes with 1,3-diketonates as bidentate oxygen donor ligands LCuIII(CF3)2 were prepared for the first time and fully characterized, including by X-ray crystallography. These complexes are bench stable and soluble in most organic solvents. Promising reactivity of Cu(III) trifluoromethyl diketonates in radical and radical–polar crossover trifluoromethylation reactions was demonstrated. Direct C–H trifluoromethylation of electron-rich arenes and indoles using Cu(III) trifluoromethyl diketonates under blue light irradiation is described. Azolo- and oxy-trifluoromethylation of terminal alkynes and S-trifluoromethylation of aromatic thiol can be achieved using LCuIII(CF3)2 in mild conditions.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/GA23-04659S" target="_blank" >GA23-04659S: Utilization of organic fluorinated azides for the synthesis of unusual nitrogen heterocycles</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Advanced Synthesis & Catalysis
ISSN
1615-4150
e-ISSN
1615-4169
Volume of the periodical
365
Issue of the periodical within the volume
17
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
2858-2864
UT code for WoS article
001038367600001
EID of the result in the Scopus database
2-s2.0-85166190651