Mechanisms of Photoredox Catalysis Featuring Nickel-Bipyridine Complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F24%3A00586787" target="_blank" >RIV/61388963:_____/24:00586787 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acscatal.4c02036" target="_blank" >https://doi.org/10.1021/acscatal.4c02036</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acscatal.4c02036" target="_blank" >10.1021/acscatal.4c02036</a>
Alternative languages
Result language
angličtina
Original language name
Mechanisms of Photoredox Catalysis Featuring Nickel-Bipyridine Complexes
Original language description
Metallaphotoredox catalysis can unlock useful pathways for transforming organic reactants into desirable products, largely due to the conversion of photon energy into chemical potential to drive redox and bond transformation processes. Despite the importance of these processes for cross-coupling reactions and other transformations, their mechanistic details are only superficially understood. In this review, we have provided a detailed summary of various photoredox mechanisms that have been proposed to date for Ni-bipyridine (bpy) complexes, focusing separately on photosensitized and direct excitation reaction processes. By highlighting multiple bond transformation pathways and key findings, we depict how photoredox reaction mechanisms, which ultimately define substrate scope, are themselves defined by the ground- and excited-state geometric and electronic structures of key Ni-based intermediates. We further identify knowledge gaps to motivate future mechanistic studies and the development of synergistic research approaches spanning the physical, organic, and inorganic chemistry communities.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Catalysis
ISSN
2155-5435
e-ISSN
2155-5435
Volume of the periodical
14
Issue of the periodical within the volume
11
Country of publishing house
US - UNITED STATES
Number of pages
22
Pages from-to
9055-9076
UT code for WoS article
001235209300001
EID of the result in the Scopus database
2-s2.0-85194965355