Triptycene-Based Tripodal Molecular Platforms
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F24%3A00598419" target="_blank" >RIV/61388963:_____/24:00598419 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/24:10490574
Result on the web
<a href="https://doi.org/10.1002/chem.202401889" target="_blank" >https://doi.org/10.1002/chem.202401889</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.202401889" target="_blank" >10.1002/chem.202401889</a>
Alternative languages
Result language
angličtina
Original language name
Triptycene-Based Tripodal Molecular Platforms
Original language description
Molecular platforms are essential components of various surface-mounted molecular devices. Here, we document the synthesis of two universal triptycene-based tripodal pedestals featuring terminal alkynes in the axial position. We showcase their versatility by incorporating them into the structures of diverse functional molecules such as unidirectional light-driven molecular motors, photoswitches, and Brownian molecular rotors using standard cross-coupling reactions. We also present their fundamental physical properties, including acidity constants, data from differential scanning calorimetry, and crystallographic analysis of two parent and five derived structures. Finally, and importantly, we demonstrate that the photochemical properties of selected photoswitch representatives remain uncompromised when fused with tripods.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
1521-3765
Volume of the periodical
30
Issue of the periodical within the volume
56
Country of publishing house
DE - GERMANY
Number of pages
16
Pages from-to
e202401889
UT code for WoS article
001312913400001
EID of the result in the Scopus database
2-s2.0-85203966019