From boom to bloom: synthesis of diazidodifluoromethane, its stability and applicability in the 'click' reaction

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F25%3A00604237" target="_blank" >RIV/61388963:_____/25:00604237 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/25:43931706 RIV/00216208:11310/25:10489906 RIV/00216275:25310/25:39921792
Result on the web
<a href="https://doi.org/10.1039/D4CC05128A" target="_blank" >https://doi.org/10.1039/D4CC05128A</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d4cc05128a" target="_blank" >10.1039/d4cc05128a</a>

Result language
angličtina
Original language name
From boom to bloom: synthesis of diazidodifluoromethane, its stability and applicability in the 'click' reaction
Original language description
Diazidodifluoromethane was prepared from dibromodifluoromethane, sodium azide and an alkanethiolate initiator. It represents the first example of a diazidomethane that is stable enough to be used in synthesis. The stability of (poly)azidomethanes was explored with ab initio calculations. Copper(i)-catalysed azide-alkyne cycloaddition of the title azide with alkynes afforded difluoromethylene-containing bis(1,2,3-triazoles)amenable to Rh(ii)-catalysed transannulation with nitriles to difluoromethylene bis(imidazoles).
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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