The synthesis and structural aspects of the perbromo-functionalised thiaboranes closo-SBnBrn (n = 5, 9, 11): the solid-state structure of the octahedral closo-SB5Br5, governed by strong dihalogen contacts

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F25%3A00617038" target="_blank" >RIV/61388963:_____/25:00617038 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/25:00617038
Result on the web
<a href="https://doi.org/10.1039/D4CC06334A" target="_blank" >https://doi.org/10.1039/D4CC06334A</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d4cc06334a" target="_blank" >10.1039/d4cc06334a</a>

Result language
angličtina
Original language name
The synthesis and structural aspects of the perbromo-functionalised thiaboranes closo-SBnBrn (n = 5, 9, 11): the solid-state structure of the octahedral closo-SB5Br5, governed by strong dihalogen contacts
Original language description
Co-pyrolysis reactions of B2Br4 with S2Br2 at 350 °C in vacuo yielded the brominated thiaboranes closo-SB5Br5 (1), closo-1-SB9Br9 (2) and closo-SB11Br11 (3), confirmed by high-resolution mass spectrometry, experimental and computational 11B NMR spectroscopy. The strong Brδ+(σ-hole)⋯Brδ−(ring) attraction has been the decisive energy contribution in the crystal of 1.
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
<a href="/en/project/GA23-05083S" target="_blank" >GA23-05083S: Modeling Biologically Active Heteroborane Clusters</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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