Emerging Trends in Advanced Materials for C―S Coupling Reactions: Design Strategies and Future Perspectives
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F25%3A00639584" target="_blank" >RIV/61388963:_____/25:00639584 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1002/smll.202505046" target="_blank" >https://doi.org/10.1002/smll.202505046</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/smll.202505046" target="_blank" >10.1002/smll.202505046</a>
Alternative languages
Result language
angličtina
Original language name
Emerging Trends in Advanced Materials for C―S Coupling Reactions: Design Strategies and Future Perspectives
Original language description
The carbon─sulfur (C─S) bond is an essential structural unit in various therapeutic agents, including antibiotics and anticancer drugs. C─S coupling reactions involving organothiols and aryl electrophiles have emerged as a powerful strategy. Recently, C─S coupling using heterogeneous catalysts like metals, metal oxides, and single-atom sites on polymers, 2D materials, and nanoporous metal-organic frameworks (MOFs) has shown promise due to synergistic properties enhancing nanoscale dispersion, stability, activity, recyclability, and control over key textural parameters. This review highlights the design, synthesis, and catalytic behavior of nanomaterials and their supports for C─S coupling reactions. Particular attention is given to a critical evaluation of the emergence of advanced materials, including a comprehensive discussion of the underlying reaction mechanisms and an in-depth analysis of advanced materials to enhance catalytic activity, selectivity, and stability. Furthermore, mechanistic insights derived from density functional theory calculations are discussed to support the rational design and development of efficient and selective catalysts. Finally, recent advancements, emerging trends are summarized, and strategic insights for the design of next-generation catalysts with enhanced efficiency in C─S bond-forming transformations are offered.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Small
ISSN
1613-6810
e-ISSN
1613-6829
Volume of the periodical
21
Issue of the periodical within the volume
39
Country of publishing house
US - UNITED STATES
Number of pages
24
Pages from-to
e05046
UT code for WoS article
001542993900001
EID of the result in the Scopus database
2-s2.0-105012220488