Photogeneration and visualization of a surface-stabilized dinitrene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F25%3A00643502" target="_blank" >RIV/61388963:_____/25:00643502 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/25:00643502 RIV/68407700:21340/25:00382063 RIV/61989592:15640/25:73630835
Result on the web
<a href="https://hdl.handle.net/11104/0373421" target="_blank" >https://hdl.handle.net/11104/0373421</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202502640" target="_blank" >10.1002/anie.202502640</a>
Alternative languages
Result language
angličtina
Original language name
Photogeneration and visualization of a surface-stabilized dinitrene
Original language description
Nitrenes are known as key intermediates in various chemical reactions. Nitrene transfer reactions are particularly effective for synthesizing nitrogen-containing compounds, where metal catalysts play a crucial role in controlling nitrene reactivity and selectivity. In this study, we demonstrate the formation of a stable surface-supported dinitrene on Au(111) through UV irradiation of its diazide precursor, characterized by scanning probe techniques. The photoreaction mechanism is elucidated with wavelength-dependent experiments and time-dependent density functional theory calculations. Our findings present the first real-space visualization of a metal nitrene adsorbed on a surface, highlighting its potential in catalysis and surface functionalization.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie - International Edition
ISSN
1433-7851
e-ISSN
1521-3773
Volume of the periodical
64
Issue of the periodical within the volume
20
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
e202502640
UT code for WoS article
001438999900001
EID of the result in the Scopus database
2-s2.0-86000067540